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TITLE
DEDICATION
STATEMENT
CERTIFICATE
ACKNOWLEDGEMENT
CONTENTS
PREFACE
ABBREVIATIONS
1 AN INTRODUCTION TO THE CYCLOADDITION CHEMISTRY OF o-QUINONES AND o-THIOQUINONES
1.1 General
1.2 General Introduction to o-Quinones
1.2.1 Cycloaddition Reactions of o-Quinones
1.2.1.a o-Quinone as Carbodiene
1.2. I.b o-Quinone as Heterodiene
1.2.1.c o-Quinone as Dienophile
1.2.1.d o-Quinone as Heterodienophile
1.2.1.e o-Quinone as Dipolarophile
1.3 General Introduction to o-Thioquinones
1.3.1 Synthesis of o-Thioquinones
1.3.2 Cycloaddition Reactions of o-Thioquinones
1.3.2.a o-Thioquinone as Heterodiene
1.3.2.b o-Thioquinone as Heterodienophile
1.4 Importance of 1, 4-Dioxins and 1, 4-Oxathiins
1.5 Theoretical Calculations
1.6 Definition of the Problem
1.7 References
2 CYCLOADDITION REACTIONS OF o-THIOQUINONES WITH ACYCLIC, CARBOCYCLIC AND HETEROCYCLIC DIENES
2.1 Introduction
2.2 The Present Work
2.3 Results and Discussion
2.3.1 Cycloadditions with Acyclic Dienes
2.3.2 Cycloadditions with Carbocyclic Dienes
2.3.3 Cycloadditions with Heterocyclic Dienes
2.4 Theoretical Calculations
2.5 Experimental
2.6 References
3 CYCLOADDITION REACTIONS OF o-THIOQUINONES WITH FULVENES
3.1 Introduction
3.2 The Present Work
3.3 Results and Discussion
3.4 Theoretical Calculations
3.5 Experimental
3.6 References
4 CYCLOADDITION REACTIONS OF o-THIOQUINONES WITH ALKENES AND ALKYNES
4.1 Introduction
4.2 The Present Work
4.3 Results and Discussion
4.3.1 Cycloadditions with Alkenes
4.3.2 Cycloadditions with Alkynes
4.4 Experimental
4.5 References
SUMMARY
LIST OF PUBLICATIONS