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Thesis Details
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326
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Title
CERTIFICATE
DECLARATION
ACKNOWLEDGEMENT
DEDICATION
CONTENTS
1. Introduction
1.1. General
1.2. Radiation chemistry
1.3. Fenton chemistry
1.4. Ozone chemistry
1.5. Objectives
2. Materials and methed
2.1. Materials
2.2. Radiation chemical studies
2.3. Fenton reaction
2.4. Ozonolysis
2.5. Analytical instruments
3. Reactions of hydroxyl radical (OH) and hydroxymethyl radical (CH2OH) with amino, methyl, hydroxy avd methoxy substituted pymidines in aqueous medium: A pulse and steady state radiolysis study
3.1. Reactions of hydroxyl radicals (OH) with amino substituted pyrimidines
3.2. Reactions of hydroxymethyl radical and OH- with substituted pyrimidines
4. Fenton chemistry of 1, 3-dimethyluracil
4.1. Fenton reactions of DNA model systems
4.2. Kinetics of the Fenton reaction
4.3. HPLC detection and isolation of 1, 3-dimethyluracil glycol
4.4. Gamma radiolysis and Fenton reactions in deoxygenated solution
4.5. Products in the presence of dioxygen
4.6. Pulse radiolysis
4.7. Computer simulations
4.8. Summary and conclusions
5 Rate constants and product studies of the reactions of ozone with nucleobases, nucleotides, and related compounds in aqueous medium
5.1. General
5.2. Determination of rate constants
5.3. Product studies of the reactions of ozone with thymine and thymidine
5.4. Summary and conclusions
References