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Title
DEDICATION
CERTIFICATE
DECLARATION
ACKNOWLEDGEMENT
CONTENTS
Preface
1 General Introduction
1.1 The Glassy State
1.2 Definition of a Glass
1.3 Formation of Glass
1.3.1 Glasses Front Melts
1.3.2 Sol-Gel Processing
1.4 Structure and Topology
1.5 Glass as Laser Host
1.6 Spectroscopy of Rare Earths in Glass
1.6.1 Judd-Ofelt Theory
1.6.2 Energy Transfer in Doped Glasses
1.6.3 Phonon Sideband (PSB) Spectroscopy
1.7 Sol-Gel Thin Films and Applications
1.7.1 Luminescent Antireflection Coatings (LARC)
1.7.2 Fiber Optic pH Sensors
References
2 Spectral and Laser Analysis of Mn2+: Pr3+System in Phosphate Glasses
2.1 Introduction
2.2 Experimental
2.3 Spectroscopic Parameters
2.4 Radiative Transition Parameters
2.5 Nonradiative Decay Processes
2.6 Results and Discussion
2.7 Conclusions
References
3 Modified Judd-Ofelt Analysis of Pr3+ in Silica and Phosphate Glasses
3.1 Introduction
3.2 Theoretical Model I
3.3 Theoretical Model II
3.4 Experimental
3.5 Results And Discussion
3.6 Conclusions
References
4 Phonon Sideboards and Local Vibrational Analysis of Eu3+ Doped Glasses
4.1 Introduction
4.2 Experimental Procedure
4.3 Theoretical Background
4.4 Results and Discussion
4.5 Conclusions
References
5 Synthesis Characterisation and Applications of Sol-Gel Thin Films
5.1 Introduction
5.2 Theory of Sol-Gel Dip Coating
5.3 PC Based Dip Coating System
5.3.1 Hardware Description of the System
5.3.2 Mechanical Part of the System
5.3.3 Software for the System
5.4 Luminescent Antireflection Coating (LARC) as Solar Collectors
5.4.1 Efficiency of Solar Cells
5.4.2 Film Formation
5.4.3 Optical Response of the Films
5.4.4 Photovoltaic Characteristics
5.5 Evanescent Wave Based Fiber Optic pH Sensor (Optode)
5.5.1 Experimental Procedure
5.5.2 Results and Discussion
5.6 Conclusions
References
APPENDIX A